Adjusting the ailerons is not going to take any left or right pressure off the stick. What it will do for you is put the stick where you want it, but you will have to hold it there...
If you had flaps you could put some "twist" in them and it would perhaps be a substitute for proper rigging.
Also if you are not holding that much pressure you could put a tab on one aileron and rudder until you get around to re-rigging it.
Dollars to donuts, you have more twist in one wing... If that's the case, redoing one rear lift strut length may do it for you.
The farther out on the wing the more leverage, so it does not take much to make a noticeable difference.